Zinc is an important element that is found widely in biological systems, is cheap to manufacture relative to other metals, and has low toxicity. However, unlike other similar metals that exhibit a variety of vibrant colors in metal complexes, seeing different colors for zinc materials was not thought possible. In a study published in Angewandte Chemie International Edition, researchers from the Institute of Industrial Science, The University of Tokyo, have synthesized a complex with two zinc ions that does exhibit color—greatly expanding the potential properties of zinc complexes. Dramatic color changes are often used to demonstrate chemical reactions for fun; however, they can also have important uses in indicators, sensing, and smart materials. For certain metal complexes these changes happen because visible light has just the right energy to move electrons between the orbitals—the parts of the atom structure that accommodate the electrons. However, the energy gap between such orbitals of zinc's most stable ion is much larger than the energy of visible light, so the electrons can't be moved between the orbitals—and therefore can't produce color.
The Nickel-Zinc Binary System
Phase Poll #13 concluded yesterday with a pretty even split between the two elements. Nickel got slightly more votes with 51.5%, and zinc slightly less with 48.5%. Before we move into the properties and applications of nickel-zinc alloys, let’s talk a little about what we’ve already learned about phase diagrams.
From the left and right sides, we can see that zinc is fairly soluble in nickel, but that nickel is not soluble in zinc. We can also tell, without knowing anything about the periodic table, that zinc and nickel are close to each other, given that the atomic and weight percents are fairly similar. Despite their proximity on the periodic table though, we can see from the phase diagram they have vastly different melting temperatures, with zinc melting at over 1000°C less than nickel.
The primary application of this binary system is in corrosion-resistant coatings. While pure zinc coatings were once more common, small amounts of nickel help to increase the corrosion resistance. These coatings usually contain around 85% zinc or 15% nickel, resulting in the γ phase shown in the above diagram. Not only does this phase provide better corrosion resistance, but it is more ductile as well, allowing for easier coating. However, nickel remains much more expensive than zinc, limiting applications of such coatings.
The middle of the phase diagram is less well studied, and alloys with equal parts nickel and zinc are uncommon. It is known that the β1 phase crystalizes with a CuAu type structure.
Sources/Further reading: ( 1 - image 1 ) ( 2 - image 2 ) ( 3 - images 3 and 4 ) ( 4 ) ( 5 )
More phase diagrams: ( mole fraction ) ( mole fraction and mass fraction )