Depending on their surface tension, coalescing drops can create or suppress surface jets as they merge. (Image, research, and submission credit: T. Sykes et al., arXiv)
It looks like the fiery edge of a star’s corona, but this photo actually shows a dissolving droplet. The droplet, shown as the lower dark region in this shadowgraph image, is a mixture of pentanol and decanol sitting in a bath of water. Pentanol is a type of alcohol that is fully miscible with decanol and is water soluble, so that it will dissolve into the surrounding water over time. Decanol, on the other hand, is immiscible with water, so that part of the droplet won’t mix with the surrounding water.
The bright swirls along the droplet’s edge show areas with more pentanol. As the alcohol dissolves into the water, it forms a buoyant plume at the top of the droplet that rises due to pentanol’s lower density. That rising plume draws fresh water in from the sides, shown by the upper white arrows. Inside the droplet, flow moves in the opposite direction, from the top toward the outer edges. This is a result of uneven surface tension within the droplet. Scientists are interested in understanding the dynamics of these multiple component drops for applications like printing, where it’s desirable for pigments in an ink drop to be distributed evenly as the drop dries. (Image credit: E. Dietrich et al.)
The shape of a droplet sitting on a surface depends, in part, on its surface tension properties but also on the nanoscale roughness of the surface. Small variations in the height and shape of the surface will change the area a drop contacts as well as the contact angle the edge of the drop makes with the surface. If the contact line between the drop and surface stays the same as a droplet evaporates into the surrounding gas or dissolves into the surrounding liquid, then we say the drop is pinned. A pinned drop’s contact angle will decrease as the drop’s volume decreases. This strains the ability of the nanoscale roughness to keep the drop’s edge pinned. As individual points of contact fail, the drop’s edge may jump inward to a new contact point. This set of discrete jumps between pinned states is called a stick-jump or stick-slip mode. (Image credit: E. Dietrich et al., source; see also: E. Dietrich et al. 2015)
One of the joys of science is the sense of discovery that can come even from looking at something seemingly simple. Take, for example, a water droplet sitting on a plate. If you slowly tilt the plate, the droplet’s shape will shift until a critical angle where it starts sliding down the plate. But what happens to two initially different droplets? As this video shows, tilting two droplets of initially different shapes and returning them to horizontal causes the droplets to assume the same shape. There’s a universal behavior at work here--like nature has a kind of reset button that makes gravity and surface tension work together such that a droplet will assume a preferred shape. For an experimentalist, it’s certainly a handy way to create repeatable experiments! (Video credit: M. Musterd et al.)