Songshan These incredible rocks make up what is known as Shuce Cliff, one small part of the Songshan or Mount Song complex in northern China. Found in China’s Henan Province, Songshan is a geological complex consisting of 5 summits and ridges, the highest of which reaches 1512 meters above sea level. The area is also filled with religious significance, including the presence of Taoist temples and the Buddhist Shaolin Temple where Zen Buddhism is believed to have been founded. The area is also a UNESCO global Geopark, recognizing its geological and historical contributions to the world.
Eudialyte syenite
Isn’t that a delightful color? The mineral with the strong color is Eudialyte, a fairly rare mineral found in igneous rocks with a unique composition. Eudialyte’s crystal structure has a number of rare elements in it, typically including zirconium and some of the rare earth elements, in addition to the silica species that make up the backbone of the mineral.
To form Eudialyte, the first step is concentrating zirconium, rare earth elements, and sodium in a molten rock. These concentrations are only commonly found in magmas that have crystallized a lot – molten rock generated by directly melting the mantle will be very dilute in those elements. Forming this mineral requires concentrating those elements by crystallizing out other components and removing them from the magma, concentrating elements that only form rare minerals like this one – sort of like distilling alcohol to higher concentrations (sometimes the magma will also exchange elements with the rocks that surround the magma chamber holding it, enhancing the concentrating effect).
Eudialyte also forms from magmas that are “silica undersaturated”, meaning they don’t have enough silicon in them to form quartz. There are too many other atoms – sodium, rare earth elements, zirconium, etc., in the magma to allow quartz to form.
In this rock, the Eudialyte is surrounded by feldspars, biotite, and aegirine, which require aluminum, potassium, and sodium to form, in addition to the silicon backbone. This rock was found in Brazil and formed as part of a slow-cooling magma with that interesting composition.
-JBB
Image credit: https://flic.kr/p/Uatg
Diamonds are forever and Zircons are too
Many people have heard the saying ‘diamonds are forever’ but very few know about Zircon, a mineral that, at the very least, should be recognised for its longevity. The zircon below (0.0157 inches long) from the Jack Hills in Australia is the oldest rock fragment on Earth at 4.375 billion years old! To put this in perspective, that is only 165 million years after the Earth formed and less than 100 million years later than the massive impact event that produced our moon.
So what makes a Zircon so special? We have all heard of the impressive properties of diamonds, they sit at the top of the Mohs Scale of hardness after all, but this isn’t the only attribute you need to live forever.
Zircon belongs to a group called the nesosilicates, a collection of minerals defined by isolated SiO4 ions that are connected by interstitial cations (small atoms or ions that occupy the space between larger ions or atoms), in this case Zirconium. The mineral can come in a wide variety of colours, with gem quality specimens known as Matura-diamonds due to their resemblance to the real thing.
One of the key properties of Zircon is that it is chemically inert. This means it won’t react with other elements and therefore retains its chemical composition over time. It is also very hard, coming in at 7.5 on the Mohs Scale of Hardness; pretty impressive when you consider that a steel nail is only 6.5.
Furthermore, zircon is present in sedimentary, igneous and metamorphic rocks, meaning it will be present in a wide variety of samples. The minerals also contain Uranium and Thorium, allowing them to be radiometrically dated even if they are billions of years old. So, how do you make sure you win the award for oldest piece of rock? It’s easy as one, two three:
- Be abundant - the more of you there are and the more rock types you can occur in the higher the chance you’ll be found at the surface!
- Be hardy - you’ve got a whole lot of weathering, erosion and chemical alteration to survive if you are going to exist for over 4 billion years (The zircon from Jack Hills is thought to have originally formed in a granite, a very different rock to the one it is hosted in now!)
- Be dateable - There is no point in existing for billions of years and making your way to the surface just so a geologist can look at how shiny you are! Containing radioactive Uranium and Thorium is a sure fire way of getting dated and appreciated for the wonder you really are!
So there you have it, next time someone tells you diamonds are forever, just spare a thought for humble little Zircon, the oldest mineral on Earth.
- Watson
Further Reading: http://bit.ly/1hPc5DO http://bit.ly/1FDLUrI
Image Credit: John Valley – Univeristy of Wisconsin-Madison Rob Lavinsky - Irocks.com
Zircon growth rings.
Zircons usually occur as rare and tiny minerals in the rock. They grow slowly as the magma in the Earth’s crust cools down. This slow growing process is captured here by the concentric rings just like in the tree, however the age order of these rings is reversed in this case (center crystallizes first and outer ring last).
What you are looking at is a single zircon grain that is about 0.01 mm across. This grain has been cut in half to reveal it’s inner structure by an imaging method called cathodoluminescence.
The Sixtymile formation: last of the Supergroup and the start of the Cambrian
The Grand Canyon "Supergroup" has been our home for nearly 10 posts over the last 2 weeks. It contains numerous geologic units and formed over about 700 million years of Earth's history - tracking the formation and breakup of the supercontinent Rodinia. All of these units have one thing in common - they have been tilted, in contrast to the rocks above. Tomorrow I'll talk about what it means to be a supergroup in geology and what we learn from the fact that these rocks were tilted, but before we get to that we have one more sedimentary unit to cover.
Our last units, the Galeros formation and the Kwagunt formation, are part of the Chuar group - a thick sequence sedimentary rocks reflecting rifting as the supercontinent Rodinia broke up. These units, together with the underlying Nankoweap formation, are sediments that flowed into growing basins about 800 to 700 million years ago. They are sometimes put together and described as part of a larger packet of rocks known as the Chuar group. On top of the shales of the Chuar group sits one last unit of sedimentary rocks before things change enormously - the sixtymile formation. The Sixtymile formation is a fairly thin unit named for Sixtymile canyon (it is not 60 miles thick) Where observed, at most it is about 60 meters thick.
The last few units we saw were shales, deposited in quiet water. Over a few meters at the top of the Kwagunt formation, the unit changes conformably into the Sixtymile formation. This formation starts as a mixture of siltstones and sandstones and grades upwards into quartzites, sandstones, and even a conglomerate/breccia layer. These rocks were deposited where there was fast flowing water, with rivers and sometimes beaches in the area.
The Sixtymile formation is only exposed in a few places at the top of the Chuar group. The rocks of this group are found in an area dropped downwards by a large normal fault and are bent and twisted into several gentle folds. The close relationship between the Sixtymile formation and the nearby faulting suggests that it was being deposited as the rocks were actively folding. As the land rifted apart, blocks dropped down and opened space where water pooled. Sediments flowed into these pools, creating the Sixtymile formation. This faulting didn't just tilt this unit - it also tilted all of the units below.
The boundary between the Sixtymile formation and the Chuar group beneath it has been found to represent over 200 million years of Earth's history. The last unit of the Chuar group, the Kwagunt formation, may have formed just as glaciers were beginning to grow at the poles. Eventually, these glaciers got so big they covered and froze the entire planet twice - a state known as Snowball Earth. The sedimentary record of those snowball events is entirely missing from the Grand Canyon - there are only rocks older than that event and the Sixtymile Formation, which is younger.
Recent work by scientists at the University of New Mexico collected samples of the mineral zircon from this unit - that mineral does a spectacular job of dating rocks. They found that this unit contains zircons that are as young as 527 million years. Zircons form when they are created in igneous and metamorphic rocks, not sedimentary rocks like this one, but when they are found in sedimentary rocks they give a "Maximum age" - meaning the sediment can't be older than the zircons that it holds. You can't have 527 million year old zircons in a 600 million year old sandstone - the sandstone has to form after the zircons were created and eroded. That age means we started at the bottom of the Grand Canyon deep in the Precambrian and we have now arrived at the Cambrian - the time when multicellular life and organisms with hard parts took over the planet. In the next unit we'll find evidence of those organisms, and a whole lot of other geologic changes.
-JBB
Image credits: http://www.nature.nps.gov/geology/parks/grca/age/index.cfm https://www.flickr.com/photos/grand_canyon_nps/6517544663/in/photolist-aVW7XH-9SrArP
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The Nankoweap formation.
The Nankoweap formation is the next unit up in the Grand Canyon, found atop the last unit – the Cardenas basalt. The Cardenas can be spotted near the bottom in this wide-angle view of the Canyon. See the black unit that has a dip to it, beneath the flat lying and younger sediments? That’s the Cardenas basalt. The layers on top? That’s the Nankoweap formation.
The Nankoweap formation sits on top of the big thick Cardenas basalt. The boundary between the two units is an unconformity; there are places where the basalt was eroded before sediments started depositing on top. There are also faults which cut through portions of the Cardenas basalt but do not cut the Nankoweap formation, making this unit clearly younger.
The rocks of this formation are sandstones with hematite cement, giving them a reddish color. The lower part of the Nankoweap is fairly finely-bedded while the upper portion has coarser beds.
Paleomagneticists have worked on this unit and found that the lower and upper portions of the Nankoweap record strongly different magnetic directions. This change implies that there is a lot of time missing in the middle of the Nankoweap – a disconformity, an unconformity that sits somewhere but doesn’t have major changes in rock type. The Nankoweap is younger than the Cardenas; zircons present in this unit are as young as 780 million years old, meaning the Nankoweap formation must be younger than that age. Its hard to tell when Nankoweap deposition started but this unit could potentially represent over 100 million years of time, and isotope changes within the unit suggest parts of it were being deposited 750 million years ago.
Like the quartzite below, this rock is composed of sandy sediments derived from erosion of the surrounding areas. There are some pieces of the Cardenas basalt in the Nankoweap, mixed with quartz and feldspar grains. The Nankoweap formation contains a variety of sedimentary structures like mud cracks and ripple marks, indicating that it was deposited in a setting like an arid lake or arid shoreline where the water would appear and disappear as precipitation patterns changed.
-JBB
Image credits: https://upload.wikimedia.org/wikipedia/commons/e/ea/View_from_Lipan_Point.jpg http://en.wikipedia.org/wiki/Cardenas_Basalt#mediaviewer/File:Grand_Canyon_landscape.jpg
Sources: http://bulletin.geoscienceworld.org/content/117/11-12/1573.full https://www.researchgate.net/publication/313843847_Synthesis_of_the_780-740_Ma_Chuar_Uinta_Mountain_and_Pahrump_ChUMP_groups_western_USA_Implications_for_Laurentia-wide_cratonic_marine_basins
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Bass Formation
In the Grand Canyon, the oldest rocks are highly metamorphosed schists and gneisses – considered parts of the continental basement. These rocks are only reached in the inner gorge of the Colorado River, where the river has eroded through the entire sedimentary sequence of the western United States. The top of those metamorphic units is a called a nonconformity – it is a rough, erosional surface, created when the ancient metamorphic rocks were exposed at the surface for millions of years. The metamorphic rocks of the Grand Canyon formed about 2-1.7 billion years ago, then 10% of the age of the planet passed before anything else was recorded at this site. Atop those igneous and metamorphic rocks sits a small set of tilted sedimentary rocks known as the Bass Formation or the Bass Limestone. This is the first fairly pristine sedimentary rock we find while walking up the Grand Canyon. The features in the first photo are mostly stromatolites; layers of limestone and other sediments believed to be created as mats of bacteria grew on the floors of shallow, warm oceans. The second photo was taken at the Phantom Ranch Boat Launch deep in the Canyon’s inner gorge. Look around the people – all the rocks are pretty massive, there’s no obvious layering anywhere near the people. The only place where you see layered rocks is atop the ridge in the distance – those rocks are the Bass formation. All of the lower rocks are the igneous and metamorphic rocks of the inner gorge. The Bass Formation is the lowermost member of what is known as the Grand Canyon Supergroup. The Supergroup is a series of sedimentary rocks formed in the late Precambrian, exposed at the bottom of the canyon as a sequence of rocks that have been tilted and dip off to the northeast.
The Bass is a sequence of sedimentary rocks. It contains many layers of dolomite that probably originally formed in the ocean as limestone and then were altered to dolostone after they were buried, with thin layers of sandstone, siltstone, and the occasional coarse grained conglomerate. The stromatolites are fossil bacteria colonies that formed in the ocean This sedimentary sequence indicates that water levels were changing – from rivers that deposited the conglomerates to shallow ocean waters that formed the dolomite. This unit marks the first step in a transgressive sequence – water levels were rising to cover the exposed Vishnu Schist basement rocks, and those rising waters produced this rock unit.
Geologists look for layers of volcanic ash in sedimentary rocks like this one because we are easily able to produce age dates by measuring isotope ratios in those layers. An isotope measurement on this rock gave an age of 1254 million years old. After the big tectonic events that formed the crust of the western US, that’s when the next stage – the sedimentary stage – began.
-JBB
Image credit: NPS https://www.flickr.com/photos/grand_canyon_nps/6705376193/in/photostream/ https://www.flickr.com/photos/grand_canyon_nps/8229636485/
Reference: https://bit.ly/2REaVCr By the way, we’re going to be in the Grand Canyon Supergroup for a while.
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To most people, diamonds are the most valuable mineral, but to most geologists, that may be zircon. Even more than diamond, they really do last forever, being the oldest thing humans have yet discovered on Earth (see our older post http://tinyurl.com/k9668zp). They are also valuable to geologists in their time-keeping ability. Unlike diamond, and many other minerals, you can directly tell when it was formed by radioactive decay of Uranium into Lead. The combination of the durability and the time-keeping make Zircon useful to find ages of rocks even after they have been metamorphosed! Mr. A Image Credit: Chd (http://en.wikipedia.org/wiki/File:Zircon_microscope.jpg)
Provenance If you are a fan of art, archeology, or other ancient collectables, you might have used the word "provenance" before. It turns out geologists use the word in a similar way. Provenance is the process of figuring out where something came from. In geology, this is mainly used with sedimentary rocks. It can be done with a type of sedimentary grain, or even with a date, as in the case of detrital zircon. Since zircon grains are so durable and yet keep time, their ages can be used to see the various source rocks that contributed to a sedimentary rock, like in this plot from a USGS study in Alaska. -Mr. A Alaskan study: http://pubs.usgs.gov/pp/1760/f/ Image Credit: USGS
Oldest bit of Earth yet found!
Zircons are tough little devils! They’re hard (7.5 on the Moh’s scale), do not melt or metamorphose easily (the melting point of zircon is over 2500 C), essentially they’re nearly indestructible. So, when a zircon is born from some magmatic event (or the melting of a previous solid rock), they tend to record for all posterity the oxygen isotope ratios of their general environment, and include enough uranium-thorium-lead to provide a geochronometric clock.
This little zircon has apparently been hanging around for ~4.4 billion years. Okay, its dark blue core is 4.4 billion, the clear growth (also zircon) surrounding it is about 1 billion years younger. This means it originally crystallized ~114 million years after the original formation of the Earth from the solar nebula! It is considered the oldest little bit of the Earth yet discovered.
Zircons provide the best tools known so far for following early Earth history: studying zircons of various old ages can show an evolution of oxygen ratios that indicate when conditions suitable for life were developed, even possibly suggesting the presence of liquid water. The fact that the zircons exist at all indicates that a solid silicate rock-based (rather than magmatic ocean-covered surface) was already in existence. In younger geologic environments, such as today’s Mid-Atlantic Ridge, some old zircons of 300 million years in age and even 1.6 billion years in age have been recovered hosted in recent lava eruptions: these are taken to indicate the “recycling” nature of the Earth’s lithosphere. Those indestructible little zircons have somehow made it from older continental sources, through the plate tectonic cycle, and have returned to the Earth's surface via volcanic activity.
Why blue? Most blue zircons that you buy as jewelry are heat treated to change the zircon’s original color (usually a mucky red brown) back to a pristine-appearing sparkling colored gem. But blue zircons can occur naturally (possibly a natural heat treatment with that clear zircon rim was added?). Oh, by the way, another fun fact about zircons is that they’re fluorescent in ultraviolet light! This zircon is being viewed in ultraviolet light so that it fluoresces, that way scientists can see the layering in the crystal and figure out which corner of it grew first.
This zircon was located in a gneiss craton in Western Australia, where other very old zircons have also been located. If you like the Archean, read our Earth Story post: http://tinyurl.com/mgdfhst
Annie R Photo downloaded from the NPR article: http://www.pbs.org/wgbh/nova/next/earth/4-4-billion-year-old-crystal-is-the-oldest-piece-of-earths-crust/ Also read is you wish: http://www.nature.com/ngeo/journal/vaop/ncurrent/full/ngeo2075.html http://www.nature.com/nature/journal/v393/n6686/full/393676a0.html http://minerals.gps.caltech.edu/files/Visible/zircon/Index.htm_ _
Science
There is a tag saying this was animated.
The history of the Yellowstone hotspot
This photo comes from an area of the United States known as the Snake River Plain. The rocks you see behind the river are part of a large series of igneous rocks that scrape across the western United States from Oregon through Idaho, finally ending at Yellowstone National Park. This area really is a plain – the land is fairly flat, filled with rolling hills and gentler river slopes, but it stands out because it’s surrounded by large, steep mountain ranges on all sides.
The Snake River Plain is believed to have been sculpted by the same forces that today produce Yellowstone; giant volcanoes. For the last 15 million years or more, a hotspot has been sitting beneath the western U.S., supplying heat that has driven large volcanic eruptions.
These eruptions form calderas – large craters like Yellowstone produced when huge amounts of magma are erupted to the surface, leaving a large gap in the earth at the top of the magma chamber and causing the rocks above to collapse downward. In a sense, the Snake River Plain was formed by the Earth devouring the mountain ranges that used to be there.
Some parts of the history of this hotspot are known, some parts are less well known. It’s believed there are many calderas along the Snake River Plain, but how many eruptions have taken place is not well known because many of the older calderas have been buried by rocks from the younger eruptions. We know pretty well when the Yellowstone caldera eruptions have taken place (the most recent eruption was 640,000 years ago), but the older calderas aren’t that well constrained. Understanding the behavior of previous eruptions will give us insights into how the Yellowstone volcano might work in the future.
New research from the lab of Dr. Bindeman at the University of Oregon tells the story of one of these calderas, the Picabo caldera, located in eastern Idaho not far from where this photo was taken (close to the city of Blackfoot, for reference). The caldera itself is buried under up to 2 kilometers of younger rocks, so the remnants of most of the eruptions were hidden. However, there are a series of recent drill cores through the SRP that sample these rocks, and using those cores they tell the story of this caldera’s activity.
Based on the drilled rocks, they identify 8 distinct eruptive units that could represent eruptions from this caldera. All took place between 6 and 9 million years ago. The sizes are difficult to estimate but several were likely on the scale of the Yellowstone eruptions.
The authors also piece together how the magma chambers that gave rise to the eruptions formed. The mineral zircon is formed in magma chambers and generally does a good job of recording the chemistry of the magma that formed it.
By measuring zircon chemistries, the authors find that the first eruptions at a caldera are produced by the assembly of a series of smaller magma chambers, each with its own chemistry. These distinct magma chambers lead to the formation of distinct zircon compositions which survive until they are erupted, allowing them to be measured today.
After the first eruption(s), there is a transition. The first magmas have a variety of zircon compositions, but these are followed by eruptions with nearly-homogeneous zircon compositions.
This work therefore suggests that the mechanism for forming a caldera like Yellowstone involves a series of smaller magma chambers and eruptions that eventually join together to form the giant volcanoes. Those large calderas are then capable of multiple eruptions until they finally quiet as the magma supply moves away.
Several final details are also worth noting. First, the eruptions at this site took place roughly 500,000 years apart, similar to the age differences between eruptions recorded at Yellowstone (8 eruptions over about 4 million years). That result suggests the timing between eruptions at Yellowstone, of just over 500,000 years, is consistent through a large part of the Snake River Plain.
Finally, the timing of this caldera’s eruptions overlaps with the eruptions of two neighboring calderas. This result we’re less familiar with; only Yellowstone has erupted within the last 2 million years, but at this time, there were up to three Calderas erupting during the same time interval. This state could be one that the Yellowstone hotspot returns to in the future as it continues to migrate across the western U.S.
-JBB
Image credit: (creative commons license) http://www.flickr.com/photos/93452909@N00/5070061433/
Original paper (subscription): http://www.sciencedirect.com/science/article/pii/S0012821X13004275
Both this research project and the drilling operations funded in part by the National Science Foundation._ _
A granite is born
At first glance these rocks snapped while wandering around some old mountain roots in the Sierras de Cordoba in Argentina don't seem like much, but they record the moment in high grade metamorphism when old rocks turn into new, with nothing but a few zircons left behind to testify to their previous history. The first photo shows a mass of fine-ish grained 'baby' granite, and floating within it a large rounded chunk (in the rough centre and a few attendant blebs) of the grey and white banded gneiss from which it formed, that was still floating unmelted in the magma when it froze (and by then probably some distance from its source rock). In the second photo the act of birth is even more intimately caught. The chunks of gneiss are picked out with a white outline of fresh quartz rich melt, also frozen in place. These rocks are called migmatites and mark a generational turnover in the rock cycle, when deep crust melts (usually during a continental collision and mountain building moment), rises and freezes, becoming shallower, younger crust, potentially susceptible to uncovering and erosion into sediments, whose burial unto melting depth will start the whole cycle anew...
The first photo is of a boulder in a river bed, the area in the photo is maybe a metre squared, the second boulder is about a metre in the longest dimension.
Loz Image credit: Loz
Hunting for grains of zircon surrounded by tourmalines in a pile of sand, under a microscope