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The Earth Story

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This is the blog homepage of the Facebook group "The Earth Story" (Click here to visit our Facebook group). “The Earth Story” are group of volunteers with backgrounds throughout the Earth Sciences. We cover all Earth sciences - oceanography, climatology, geology, geophysics and much, much more. Our articles combine the latest research, stunning photography, and basic knowledge of geosciences, and are written for everyone!
We hope you find us to be a unique home for learning about the Earth sciences, and we hope you enjoy!
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Alibates Flint

Put yourself in the shoes of a person walking across this landscape 13,000 years ago. Not much topography, covered by grasses. You see these rocks lying on the surface – do you pay any attention to them?

Today, this area is in the Great Plains north of Amarillo Texas and has been recognized as a national monument because of outcrops like these. These photos come from Alibates Flint National Monument – a site that supplied early populations throughout North America with a useful resource – flint.

Flint is a type of cryptocrystalline silica, made of the same stuff as quartz but without the rigid crystal structure of a quartz crystal. Flint commonly forms when fluids interact with rocks that have silica in them; the fluids will dissolve silica in one place and precipitate it in others, forming layers of silica that don’t get enough heat to grow big crystals.

Because flint isn’t a single crystal like a grain of quartz, it doesn’t break in the same way as quartz – it fractures conchoidally, like obsidian does, allowing it to be whittled into sharp tips and used as spear points, while still retaining some of the hardness and strength of silicate minerals like quartz.

Flint grains from this site have been found in archaeological locations throughout the southern U.S. Its earliest use is about 13,000 years ago and it was used up until 1870 as gunflint – a small piece of rock used to make a spark that ignited gunpowder in flintlock muskets.

The flint at this location weathers directly out of a layer of dolomite. Dolomites are the altered remnants of limestones – fluids that wind their way through limestone deposits can convert the rock to dolomite. That same process, fluid migration through limestone, was probably able to concentrate some of the silica in the rock into single layers where it formed the flint. Today, the softer dolomite erodes away, leaving piles of flint scattered across the surface.

Where the silica in the rock came from isn’t perfectly known – most carbonates form in areas where there is very little siliceous sediment, but it could have been supplied by volcanic ash, which rains down in the ocean even far away from land when there is a large enough volcanic eruption. The dolomites in this area are Permian in age – dating back to the time of Pangea. The volcanoes that could have produced them are long since gone, but the end products shaped trade routes throughout North America during the early days of humanity’s presence in this area.

-JBB

Source: facebook.com
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Why is obsidian so useful for tools?

The ancient inhabitants of many continents knew the properties of obsidian. This black volcanic glass was a key component in tools and hunting weapons; arrowheads and shards from their production are found all over the world and trading paths between different civilizations can even be tracked using obsidian.

The reason why this rock was so useful comes from the structure of the rock. Obsidian isn’t a mineral, by definition. Minerals have a defined structure that repeats over and over again. Obsidian is what we’d call a “glass”. A mineral growing from lava needs time to grow; atoms need time to move together and form a defined structure. If lava cools off too quickly, it can instead have all its atoms locked into whatever format sat there when the magma was molten, a state we call a glass.

A glass has no defined, long-term structure, so it doesn’t break into crystal faces. This property means glasses are strong in all directions and when broken they will have what we call “conchoidal fractures”. This is different from crystals; they tend to break along fracture or “cleavage” plains controlled by the arrangement of the atoms. You can see the remnant of those fractures in the rippled breaks at the edge of this stone tool artifact; the fractures formed at a single point and widened as they broke outwards.

A skilled worker using obsidian can create a series of conchoidal fractures around the edge that bring the rock to an extremely sharp point. The angle of the tip won’t be limited by the natural crystal shape; instead the spear tip can be made both strong and sharp.

Obsidian is generally made out of high silica, rhyolitic lava. These high silica lavas are very viscous and therefore crystals don’t grow rapidly on them, making obsidian formation easy. Different obsidian compositions and structures do behave differently during processing, so some obsidian sources were highly prized and rocks that match in chemistry were traded across thousands of kilometers, covering entire continents.

-JBB

Image credit: John Atherton (Creative Commons):https://www.flickr.com/photos/gbaku/1287124990/

Source: facebook.com
Avatar

Why is obsidian so useful for tools?

The ancient inhabitants of many continents knew the properties of obsidian. This black volcanic glass was a key component in tools and hunting weapons; arrowheads and shards from their production are found all over the world and trading paths between different civilizations can even be tracked using obsidian.

The reason why this rock was so useful comes from the structure of the rock. Obsidian isn’t a mineral, by definition. Minerals have a defined structure that repeats over and over again. Obsidian is what we’d call a “glass”. A mineral growing from lava needs time to grow; atoms need time to move together and form a defined structure. If lava cools off too quickly, it can instead have all its atoms locked into whatever format sat there when the magma was molten, a state we call a glass.

A glass has no defined, long-term structure, so it doesn’t break into crystal faces. This property means glasses are strong in all directions and when broken they will have what we call “conchoidal fractures”. This is different from crystals; they tend to break along fracture or “cleavage” plains controlled by the arrangement of the atoms. You can see the remnant of those fractures in the rippled breaks at the edge of this stone tool artifact; the fractures formed at a single point and widened as they broke outwards.

A skilled worker using obsidian can create a series of conchoidal fractures around the edge that bring the rock to an extremely sharp point. The angle of the tip won’t be limited by the natural crystal shape; instead the spear tip can be made both strong and sharp.

Obsidian is generally made out of high silica, rhyolitic lava. These high silica lavas are very viscous and therefore crystals don’t grow rapidly on them, making obsidian formation easy. Different obsidian compositions and structures do behave differently during processing, so some obsidian sources were highly prized and rocks that match in chemistry were traded across thousands of kilometers, covering entire continents.

-JBB

Image credit: John Atherton (Creative Commons): https://www.flickr.com/photos/gbaku/1287124990/

Source: facebook.com
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The King of Stonehenge's teeth.

The Amesbury Archer was excavated near Stonehenge in 2002. This bronze age man died aged 35-45 between 2500 and 2300 BCE and was found buried with many fine arrow heads, hence the name. His burial is the richest grave of that era discovered so far, hinting at high status or wealth, though the man had survived injury and would have walked with a limp. Alongside the arrowheads other treasures were found: copper knives, pots from the Beaker culture, stone wrist guards and the earliest gold artefacts found in Britain. He was buried with a younger male, believed to be a relative as they shared a congenital illness that left traces on the skeleton. Dubbed by the press the King of Stonehenge, he is currently on display in Salisbury museum. Geoscience techniques are an essential part of modern archaeology, from recreating the paleo environment of excavation sites using geochemical and pollen analysis on sediments, through using geophysical exploration technology to trace graves and walls to determining whether animal bones in rubbish tips came from wild or domesticated versions. Over the last decade a technique using oxygen and strontium isotope analysis on tooth enamel has allowed us to start tracing the movements of historic peoples.

The technique was originally developed for police forensics, in order to trace the origin of buried John and Jane Does. Rapidly adopted by archaeologists, zapping teeth with lasers to analyse the gas that rises them off has become a standard tool, and has given us a few surprises. It works because the groundwater we drink when we grow up has a characteristic isotopic signature, which gets locked in to the mineral (apatite) that makes up our tooth enamel while our adult teeth grow. Obviously, people who have moved around alot as children will create confused readings, but during most of history such cases were very rare.

In the case of the Amesbury burial, the older man was found to originate from the Alpine area of central Europe (Switzerland, Austria or Bavaria), adding to the mystery of his human story. His relative on the other hand grew up in the area he was buried in (the Cretaceous chalklands of southern England). The implication is that the archer migrated to England for some unknown reason, and had a son here.

In another famous case, that of Otzi the 5300 year old iceman found thawing out of a glacier on the Austrian Italian border a couple of decades back turned out to have originated in Corsica or Sardinia. The reason for his murder remains unknown. What a wonderful thing that geoscience can tell us such a human story from the recent past.

Loz

Image credit: J. Brayne/Wessex archaeology

http://planetearth.nerc.ac.uk/features/story.aspx?id=675

http://www.smithsonianmag.com/travel/mystery-man-stonehenge.html

http://www.britishmuseum.org/system_pages/holding_area/explore/the_amesbury_archer.aspx

http://www.wessexarch.co.uk/projects/amesbury/tests/oxygen_isotope.html

http://bonesdontlie.wordpress.com/2011/05/24/strontium-isotopes-the-new-hot-archaeology-trend/

http://www.forensicmag.com/articles/2007/01/tracing-unidentified-skeletons-using-stable-isotopes#.UfP2_23YO4z

http://ir.lib.uwo.ca/cgi/viewcontent.cgi?article=1208&context=totem

A long paper on the topic: http://media.library.ku.edu.tr/reserve/resspring10/achm507_arha411_AYener/week11.pdf

Source: facebook.com
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Trading obsidian in worlds old and new.

Obsidian is a silica rich volcanic glass that has been prized for millennia because it can easily be shaped into a point, thanks to its property of conchoidal fracture (shaped like a shell). Its use in tools dates from the lower Palaeolithic, 2.6-1.7 million years ago, long before the appearance of modern humans. Being easier to work than flint, easy to carry and high in value, it was probably the first trade item in history. Since it has only limited sources, wherever a felsic volcano has erupted and the lava has rapidly cooled to a glass, it is widely used to trace early exchange networks.

Peoples who lived near a source became rich from it, and one of the earliest known towns, Catal Huyuk (7500-5600 BCE) in modern Turkey was built upon the resulting wealth. Obsidian was also passed around in the Americas soon after man's currently recognised arrival. Some of these prehistoric exchange networks are now emerging from the fogs of time, with a little help from Archaeology's friends in the Earth sciences.

Geochemical fingerprinting of volcanic rocks for both major and trace elements is a standard tool of Earth science. Back in the 1960's, Colin Renfrew (Britain's most influential prehistorian of the last century) realised that this could be used to trace distribution routes, and be of particular importance in prehistoric studies. The abundance of obsidian artefacts in excavations worldwide set Renfrew onto his idea in the first place. It is plentiful, easily traced and can be analysed non-destructively. This idea had been applied worldwide by many archaeologists, and this method is now a standard tool of the discipline.

The analysis is done using a LAICPMS (explained in the first part of this series at http://tinyurl.com/c9nba7f) for trace elements and X-ray fluorescence for the major elements. This last methods bombards the sample with radiation to excite the electrons within. These electrons absorb the energy of the rays and jump to a higher energy level. When they fall back to their default state each element gives off radiation of a characteristic wavelength. A spectrometer then measures and collates these, and delivers a printout of the samples relative elemental composition.

Meaningful data from the Paleolithic is more scarce, as the world was less densely populated, peoples nomadic and artefact finds more isolated. The Neolithic era starting in 11000 BCE saw the first towns appear, including Jericho and Catal Huyuk. It was a time of early agriculture and evolving trade in the Near East, with obsidian the main long distance good. It was used for both hunting and agricultural implements, as well as luxury goods like mirrors. A bit earlier in the Americas, similar trade in this raw material for tool making was starting with the Clovis culture, spreading out from the obsidian sources in the west.

Obsidian distribution networks have been traced all over the Americas, from California and Oklahoma to the southern cone in Argentina. It allows us to trace movement patterns, and by dating artefacts using C14 from associated organic remains such as charcoal, to learn how sources us changed over time. In some periods all the obsidian used was local, at others some pieces came from far away.

In the Mediterranean there are several major sources, each with its own dispersion pattern. They include some of the Greek islands, Sardinia, Cappadocia and Anatolia (Hassan Dag being the volcano near Catal Huyuk). They can be distinguished from each other using trace elements such as yttrium, barium and zirconium. In Sardinia and Melos, the changing pattern of use of different lava flows as sources has also been traced, along with the different places each of these were traded to.

Using Sardinia as an example, three main sources were exported, called SA, SB and SC. Southern France liked using SA (95%), while SC was more common in Northern Italy (50%). The reasons for these preferences are unknown. Maybe they reflect choice at the customer end, or that they follow the routes chosen by different traders using one source and travel pattern.

In Anatolia the two main source areas had different routes and dispersion patterns, which evolved through time. Experts theorise that in all early obsidian trade, hunting parties played a big part in the physical movement of goods. The trade evolved from a limited amount in the early Paleolithic through to agricultural tools in early pre-metalworking farming communities. The routes widened from lines along the coasts and rivers to a more trellis like pattern over time, eventually covering the whole Levant (Lebanon, Syria) as far as the Euphrates river in modern Iraq.

As the technology has gotten cheaper, analysis of the entire excavated artefact assemblage from a site has become more common, allowing us to recognise the occasional piece from further away. Before, when only a few pieces per site were analysed, the sample chosen might not have been representative. Combined with stratigraphy it allows us to constrain when a source was exploited.

The use of obsidian fades during the transition from hunter gathering to agriculture as metals began to spread, and these imported artefacts gradually disappear from the archaeological record. Long distance exchange networks begin to be replaced by trade, mediated by money as societies began to differentiate out of the Neolithic into the copper and bronze age.

Loz

Image: Obsidian Clovis point, USA, circa 11000BCE, made from Black Tank obsidian sourced 50 miles away.

Credit: Dan Boone/Rvan Belknap

http://geokult.com/2011/06/26/hasan-dag-and-catal-huyuk/

http://shell.cas.usf.edu/~rtykot/PR22%20-%20AccChemRes%202002.pdf

http://shell.cas.usf.edu/~rtykot/PR91%20Tykot%202011.pdf

http://www.archatlas.org/ObsidianRoutes/ObsidianRoutes.php

https://inlportal.inl.gov/portal/server.pt?open=514&objID=1269&mode=2&featurestory=DA_164833

http://goafar.org/AFAR/Reading_files/Obsidian-The%20Metal%20of%20the%20Maya.pdf

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