I don't feel like Orion trying to stop D-16 from killing Sentinel was because Orion felt like Sentinel deserved to live. I mean, he crashed an entire train into the guy just minutes before.
Imagine you have a chill best friend who is the voice of reason between the two of you, but he goes through a trauma that turns him into a roiling pit of rage. You keep reaching out to him and he keeps shoving you away. He is suddenly getting fusion cannon boners from beating the shit out of potential allies, and you have to beg him not to blow said ally's head off. Your friend frames this restraint as "the last time I will show mercy."
When Orion says "Don't be like Sentinel", I don't think he means "Um, have you considered that ACTUALLY this is not The Proper Way to change the government?", I think he means "You are losing yourself and it's scaring me and it's hurting you."
He was not trying to save Sentinel, he was trying to save D-16.